Primary study on the irradiation effects of high energy C+and H+on diamond‐like carbon films
作者:
Weijie Wang,
Tianmin Wang,
Buliang Chen,
期刊:
Journal of Applied Physics
(AIP Available online 1992)
卷期:
Volume 72,
issue 1
页码: 69-72
ISSN:0021-8979
年代: 1992
DOI:10.1063/1.352148
出版商: AIP
数据来源: AIP
摘要:
Diamond‐like carbon films, prepared by the dual‐ion beam sputtering method on glass substrate, were irradiated by both carbon ions (C+) and hydrogen ions (H+) under the dose of 1×1017ion/cm2and the energy of 114 and 112 keV, respectively. The as‐deposited and the irradiated films were characterized by electrical resistivity, infrared transmittance, and Raman spectroscopy. It showed that the irradiation of both the C+and the H+can lead to the decrease or even the removal of bond‐angle disorder and the increase of thesp2C‐C bond dominated crystallite size and/or number. The irradiation can also break thesp3C‐H bond. But the irradiation of C+can lead to a bigger decrease ofsp3bonds, forming a film containing moresp2bonds, and the induced film was then more graphite‐like. In irradiation of H+, however, the decrease degree ofsp3bonds is smaller and the irradiated film still showed evident diamond‐like characteristics in electrical and optical properties. The different irradiation mechanisms of the two ions on the diamond‐like carbon films are briefly discussed.
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