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The Reaction of 4‐Formylsydnone with Nitroalkanes

 

作者: Wei‐Jing Hung,   Hsien‐Ju Tien,   Hsien‐Cheng Yu,  

 

期刊: Journal of the Chinese Chemical Society  （WILEY Available online 1994）
卷期: Volume 41, issue 1  

页码: 39-45

 

ISSN:0009-4536

 

年代: 1994

 

DOI:10.1002/jccs.199400004

 

出版商: WILEY‐VCH Verlag

 

关键词: 4‐FormyIsydnone;β‐Nitroalcohol;Nitroalkene;Dinitroalkanc;EGB;2‐Nitro‐1‐[4′‐(3′‐substituted)sydnonyl]‐1‐hydroxylethane;2‐Nitro‐1‐[4′‐(3′‐substituted)sydnonyl]‐1‐hydroxylpropane;1,3‐Dinitro‐2‐[4′‐(3′‐substituted)sydnonyl]propane;2‐Nitro‐1‐[4′‐(3′‐substitute

 

数据来源: WILEY

 

摘要:

AbstractUnder various basic solutions and reaction durations, 3‐substituted 4‐formyIsydnones and nitroalkanes containing α‐active hydrogen (e.g. nitromethane and nitroethane) are converted to β‐nitroalcohols, nitroalkenes and dinitroalkanes. β‐Nitroalcohols are obtained only by electrochemical reaction on an electrogenerated base (EGB). The mechanism of overall reaction steps in particular

 

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