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EPR Study of the Kinetics of the Formation of Radicals from Dibenzoyl Peroxide on Porous Glass

 

作者: RichardG. Wiley,   HenningF. Proelss,   Raymond Chang,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1970)
卷期: Volume 4, issue 1  

页码: 187-202

 

ISSN:0022-233X

 

年代: 1970

 

DOI:10.1080/00222337008060972

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The kinetics of the formation of radicals from dibenzoyl peroxide supported on porous glass have been determined with EPR techniques over the temperature range of 25-100°C. Values of the activation energy of 18.5 and 25 kcal/mole have been observed for two differently prepared porous glass support materials.

 

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