Note Synthesis of New Poly(Amide-Hydrazide)s
作者:
J. Thanuja,
M. Srinivasan,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1989)
卷期:
Volume 26,
issue 7
页码: 1007-1014
ISSN:0022-233X
年代: 1989
DOI:10.1080/00222338908052027
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Poly(amide-hydrazide)s were originally developed to give fibers of high modulus and high strength [1]. They were generally prepared 1) from dicarboxylic acid chlorides and aminohydrazides by low-temperature polycondensation [2,3]; 2) by the phosphorylation method [4, 5]; and 3) from dihydrazides with preformed amide linkages by low-temperature polycondensation [6]. These polymers were found to be thermally stable, but they showed poor solubility in polar aprotic solvents. In this paper we report the synthesis and characterization of some new poly(amide-hydrazide)s with azo groups in the backbone, which were introduced to improve solubility.
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