EXTRACTION OF ZINC AND CADMIUM WITH SOME BIS(5'-HYDROXY-PYRAZOL-4'-OYL)ALKANES AND TRI-n-OCTYLPHOSPHINE OXIDE IN CHLOROFORM
作者:
B.A. Diantouba,
I. Guiguemde,
A. Tayeb,
G.J. Goetz-Grandmont,
J.P. Brunette,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1994)
卷期:
Volume 12,
issue 2
页码: 325-347
ISSN:0736-6299
年代: 1994
DOI:10.1080/07366299408918213
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The extraction of zinc and cadmium with bis(5‘-hydroxy-pyrazol-4’-oyljalkanes (“HL-n-LH”, n: number of methylene links), with and without TOPO, in chloroform, has been studied when possible. The formation of third phases and/or precipitates hinders a number of extractions with HL-n-LH alone: CdIIfor all extractants, ZnIIfor n < 7. The following species are extracted with cadmium: Cd(L-n-L) (TOPO)2for n = 5, 7 to 10, Cd(L-8-L)(TOPO), Cd(L-8-LH)2(TOPO)2, Cd(L-8-LH)2(TOPO), and with Zn: Zn(L-n-LH)2for n = 7 and 8, Zn(L-n-L) for n = 9 and 10, Zn(L-n-LH)2(TOPO) for n = 5 and 7, Zn(L-n-L) (TOPO) for n = 7 to 9. The polymethylene chain length effect upon the extraction processes is attributed to a relative destabilization of Zn(L-n-L) with respect to Zn(L-n-LH)2for short-chain ligands, and conversely, to a preferential solvation of Zn(L-n-LH)2(TOPO)xcomplexes by chloroform. The former may be due to some strain in the tetradentate ligand folded onto zinc. The latter is attributed to H-bond formation between the free -LH sites and the diluent. Compared with the parent compound 1-phenyl-3-methy1-4-benzoylpyrazol-5-ol the bis(acylpyrazolols) show a better Zn/Cd extraction selectivity.
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