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Disproportionation reactions between alkyl and fluoroalkyl radicals. II. Fluoro‐ and trifluoromethyl with ethyl radicals

 

作者: G. O. Pritchard,   W. B. Nilsson,   P. E. Marchant,   L. C. Case,   J. F. Parmer,   R. F. Youngs,  

 

期刊: International Journal of Chemical Kinetics  （WILEY Available online 1984）
卷期: Volume 16, issue 1  

页码: 69-89

 

ISSN:0538-8066

 

年代: 1984

 

DOI:10.1002/kin.550160109

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractCross‐disproportionation/combination ratios for CFH2and CF3with C2H5radicals have been determined to be Δ = 0.032 ± 0.012 and δ = 0.098 ± 0.020, respectively, over the temperature range 25–75°C. For the pathway that yields CFH and C2H6, δ = 0.020 ± 0.0

 

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