Calculation of the molecular weight distribution of crosslinked polymer chains using the theory of branching processes
作者:
Vladimír Vojta,
Karel Dušek,
期刊:
British Polymer Journal
(WILEY Available online 1980)
卷期:
Volume 12,
issue 1
页码: 1-4
ISSN:0007-1641
年代: 1980
DOI:10.1002/pi.4980120102
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractA numerical method for calculation of the weight‐fraction distribution resulting from random crosslinking of polydisperse primary chains is suggested. The method is based on the numerical inverse Laplace transform of the weight‐fraction generating function given by the theory of branching processes. The applicability of the method was demonstrated using the Schulz‐Zimm type distribution of primary chains. A good agreement was obtained by comparing the results with those following from the kinetic theory of crosslinking for the most probable distribution of primary chains at low degrees of crossli
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