Magneto—Mo¨ssbauer Study of Cu0.5Fe2.5O4
作者:
A. Nagarajan,
A. H. Agajanian,
期刊:
Journal of Applied Physics
(AIP Available online 1970)
卷期:
Volume 41,
issue 4
页码: 1642-1647
ISSN:0021-8979
年代: 1970
DOI:10.1063/1.1659085
出版商: AIP
数据来源: AIP
摘要:
Saturation magnetization and Mo¨ssbauer measurements at different temperatures from 4.2° to 623°K have been made on samples of composition Cu0.5Fe2.5O4sintered at different temperatures between 1210° and 1350°C and quenched to room temperature. The Mo¨ssbauer spectra consist of a superposition of two six‐line patterns, which are attributed to iron onBsites andAsites, on the basis of the change in the intensity of the spectra with the substitution of a small amount of Sc in Cu0.5Fe2.5O4. The relative isomer shifts and hyperfine fields also confirm this assignment. The internal magnetic field at the iron nucleus at 300°K isH&bgr;= 473±2 kOe andHA= 402±2kOe. The isomer shifts relative to metallic iron and theAandBsites are found to be characteristic of the iron in the trivalent state. The saturation magnetization, Curie temperature, and hyperfine fields are found to be practically independent of the sintering temperature. The ratio of the iron site occupancy factor is determined from the intensity ratio of the Lorentzian fits of the two patterns and is compared to the value deduced from magnetization measurements. The various models proposed for this system are discussed in the light of the present work.
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