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Solubility of Anthracene in Binary Alkane + Dimethyl Adipate and Alkane + Dibutyl Oxalate Solvent Mixtures

 

作者: AnitaI. Zvaigzne,   Bradley Smith,   Yvonne Cordero,   WilliamE. Acree,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1992)
卷期: Volume 25, issue 1  

页码: 51-58

 

ISSN:0031-9104

 

年代: 1992

 

DOI:10.1080/00319109208027287

 

出版商: Taylor & Francis Group

 

关键词: Anthracene solubilities;binary solvent mixtures;mathematical representation of solubility data

 

数据来源: Taylor

 

摘要:

Experimental solubilities are reported for anthracene dissolved in three binary mixtures containing dimethyl adipate with cyclohexane, methylcyclohexane andn-heptane, and in six solvent mixtures containing dibutyl oxalate withn-hexane,n-heptane,n-octane, cyclohexane, methylcyclohexane and isooctane at 25°C. Results of these measurements are used to test two mathematical representations based upon the combined Nearly Ideal Binary Solvent (NIBS)/Redlich-Kister equations and Modified Wilson model. For the systems studied, the combined NIBS/Redlich-Kister equation was found to provide the better mathematical representation with deviations between experimental and back-calculated values being on the order of ± 3% or less.

 

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