Qualitative Analysis by Photoacoustic Spectroscopy of Amorphous Uranium Tetrafluoride Deposits
作者:
H.E. Eaton,
D.R. Anton,
J.D. Stuart,
期刊:
Spectroscopy Letters
(Taylor Available online 1977)
卷期:
Volume 10,
issue 10
页码: 847-851
ISSN:0038-7010
年代: 1977
DOI:10.1080/00387017708065020
出版商: Taylor & Francis Group
关键词: Photoacoustic Spectroscopy;Uranium Tetrafluoride
数据来源: Taylor
摘要:
Recent studies concerning uranium plasma chemistry have confirmed the generally complicated nature of uranium chemistry1. Uranium plasma, generated by either rf-heating or dc arc torch argon heating of uranium hexafluoride, tends to react with its environment to produce among other compounds both fluorides and oxy-fluorides. The products are characterized as amorphous, powdery deposits. While uranyl fluoride can be identified readily by its infra-red absorption band, uranium tetrafluoride is not easily analyzed by any routine, non-destructive technique. Procedures such as Ion Scattering Spectroscopy and Secondary Ion Mass Spectrometry are expensive and time consuming; while, X- ray and electron deffraction can not overcome the amorphous nature of the plasma deposits.
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