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Isotopic analysis of nanomole gas samples by means of dynamic flow mass spectrometry

 

作者: S. Halas,   H. R. Krouse,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1983)
卷期: Volume 54, issue 4  

页码: 437-443

 

ISSN:0034-6748

 

年代: 1983

 

DOI:10.1063/1.1137412

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The sample size for conventional double collector isotope mass spectrometry has been reduced more than three orders of magnitude by using a ‘‘pushing’’ gas for precise stabilization of sample pressure. The sample is stored in a long microcontainer (50 cm, 0.5 mm i.d.) to moderate the effect of diffusive mixing of sample with the pushing gas. If the analysis is sufficiently rapid (e.g., a run of 1 min for the unknown sample between two runs on the standard), then almost total sample consumption is possible. This method retains the high precision and simplicity of dynamic flow, yet possesses the high sensitivity of static mass spectrometry.

 

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