The scope and limitations of liquid-crystalline behaviour in monosaccharide amphiphiles Comparison of the thermal behaviour of several homologous series of D-glucose derived compounds with an amino-linked alkyl chain
作者:
HenkA. Van Doren,
RalphVan Der Geest,
CornelisF. De Ruijter,
RichardM. Kellogg,
Hans Wynberg,
期刊:
Liquid Crystals
(Taylor Available online 1990)
卷期:
Volume 8,
issue 1
页码: 109-121
ISSN:0267-8292
年代: 1990
DOI:10.1080/02678299008047334
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A short review of the scope and limitations of liquid-crystalline behaviour in carbohydrate derivatives is presented. In order to investigate the influence of structure variations on the thermal behaviour of monosaccharide amphiphiles, six homologous series of D-glucose and 2-deoxy-D-glucose derivatives with an aminolinkedn-alkyl chain were prepared. The observed thermal behaviour could be readily explained with the aid of a refinement of the qualitative model that was presented earlier [1]. All compounds were found to be mesogenic, and the observed mesophase was smectic Ad(i.e. a partially overlapping bilayer structure) in all cases.
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