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Side reaction in peptide synthesis

 

作者: SHUI‐TEIN CHEN,   LEE‐CHIANG LO,   SHIH‐HSIUNG WU,   KUNG‐TSUNG WANG,  

 

期刊: International Journal of Peptide and Protein Research  （WILEY Available online 1990）
卷期: Volume 35, issue 1  

页码: 52-54

 

ISSN:0367-8377

 

年代: 1990

 

DOI:10.1111/j.1399-3011.1990.tb00720.x

 

出版商: Blackwell Publishing Ltd

 

关键词: enzymatic hydrolysis;oxazolidone;peptide synthesis;serine;threonine;urethane‐typeN‐protecting groups

 

数据来源: WILEY

 

摘要:

2‐Oxazolidone derivatives formed through an intramolecular reaction in the process of alkaline treatment of urethane‐typeN‐protected peptides of which theN‐terminal residues were Ser or Thr having unprotected hydroxyl groups. In order to avoid this side reaction, the esters of these peptides could be cleaved by enzymatic hydrolyses instead of saponif

 

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