Thermodynamic Consistency and Entropy Change in the Density-Wave Theory of Freezing
作者:
B. D'aguanno,
M. Rovere,
G. Senatore,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1987)
卷期:
Volume 16,
issue 3
页码: 157-162
ISSN:0031-9104
年代: 1987
DOI:10.1080/00319108708078515
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Thermodynamic consistency within the density-wave theory of freezing is briefly discussed. The non equivalence of different routes to calculate the change in a thermodynamic quantity upon freezing is related to the approximations involved in practical calculations. In particular, a new way of calculating entropy and volume changes is proposed. It is shown that this new route avoids an unphysical feature of the entropy formula previously proposed by other authors. The freezing of hard spheres is discussed as an illustration.
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