首页   按字顺浏览 期刊浏览 卷期浏览 Thermodynamic Consistency and Entropy Change in the Density-Wave Theory of Freezing
Thermodynamic Consistency and Entropy Change in the Density-Wave Theory of Freezing

 

作者: B. D'aguanno,   M. Rovere,   G. Senatore,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1987)
卷期: Volume 16, issue 3  

页码: 157-162

 

ISSN:0031-9104

 

年代: 1987

 

DOI:10.1080/00319108708078515

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Thermodynamic consistency within the density-wave theory of freezing is briefly discussed. The non equivalence of different routes to calculate the change in a thermodynamic quantity upon freezing is related to the approximations involved in practical calculations. In particular, a new way of calculating entropy and volume changes is proposed. It is shown that this new route avoids an unphysical feature of the entropy formula previously proposed by other authors. The freezing of hard spheres is discussed as an illustration.

 

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