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Aqueous high‐temperature chemistry of organophosphorus compounds

 

作者: AlanR. Katritzky,   JuliaV. Pervova,   PetiaA. Shipkova,   StevenM. Allin,   Michael Siskin,   H. Dupont Durst,  

 

期刊: Toxicological & Environmental Chemistry  （Taylor Available online 1997）
卷期: Volume 59, issue 1-4  

页码: 219-238

 

ISSN:0277-2248

 

年代: 1997

 

DOI:10.1080/02772249709358438

 

出版商: Taylor & Francis Group

 

关键词: Aquathermolysis;organophosphorus compounds;detoxification;warfare agents

 

数据来源: Taylor

 

摘要:

Tripropyl phosphate, triethyl phosphonoacetate, triphenyl phosphate, diethyl 2‐methylbenzyl‐phosphonate, diethyl 1‐naphthylmethylphosphonate and diethyl (4‐biphenylmethyl)phosphonate were chosen as analogs of military nerve gases. The six organophosphorus compounds were treated in neutral superheated water at sub‐ and supercritical temperature. The products of hydrolysis were identified and the potential application of aquathermolysis for the detoxification of potent military warfare agents is outlined.

 

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