The hydrogen content of plasma‐deposited silicon nitride
作者:
W. A. Lanford,
M. J. Rand,
期刊:
Journal of Applied Physics
(AIP Available online 1978)
卷期:
Volume 49,
issue 4
页码: 2473-2477
ISSN:0021-8979
年代: 1978
DOI:10.1063/1.325095
出版商: AIP
数据来源: AIP
摘要:
The hydrogen content of glow‐discharge‐deposited silicon nitride (SiN) films made at 330–350 °C has been determined. Preparation conditions were varied to produce a range of compositions of Si/N=0.7–1.4. Quantitative hydrogen profiling of the samples was carried out using the resonant nuclear reaction15N+H→12C+4He+&ggr; ray. Calibration factors for Si‐H (2160 cm−1) and N‐H (3350 cm−1) absorption‐band areas or absorbances have also been determined, enabling infrared transmission spectra to be used for hydrogen analyses of these films. All samples were homogeneous in hydrogen content and were in the range (1.6–2.1) ×1022H atoms/cm3, or about 20–25 at.&percent; H. Roughly three‐quarters of the H is bonded to Si, the remainder to N. One plasma SiO2sample made at 300 °C from SiH4and N2O was measured also, and contained 5.7 at.&percent; H, all as OH. Although there was little variation in the H content of SiN, there is a correlation between the total H concentration and the buffered HF etch rate. Some observations on the effects of the15N ion beam (6–8 MeV) on the SiN are reported. Many Si‐H and N‐H bonds are broken, but the liberated H atoms or ions are unable to diffuse out of the film.
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