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Reaction Mechanisms of a Nitrogenase Model. Water and Hydrogen as Reducible Substrates of the Titanocene System

 

作者: Jean-Claude Marchon,   Antonio Barbosa,  

 

期刊: Analytical Letters  （Taylor Available online 1972）
卷期: Volume 5, issue 12  

页码: 897-904

 

ISSN:0003-2719

 

年代: 1972

 

DOI:10.1080/00032717208062154

 

出版商: Taylor & Francis Group

 

关键词: Nitrogen fixation;homogeneous catalysis;titanocene;nitrogenase;hydrogen reduction;hydride ligands;ESR spectroscopy;hydrophobic sites

 

数据来源: Taylor

 

摘要:

Titanocene nitrogen fixation in tetrahydrofuran was significantly affected by traces of water. Water was reduced to hydrogen by titanocene monochloride. In turn, hydrogen was reduced to hydride by titanocene. Analogy with nitrogenase catalysis is discussed.

 

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