Infrared Kinetic Study of the Catalyzed and Uncatalyzed Reaction of Butanol-1 with α-NaphthyIisocyanate in Various Solvents
作者:
Anh-Hung Ngwen,
Ernest Marechal,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 16,
issue 4
页码: 881-895
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108056833
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The condensation reaction of α-naphthylisocyanate with n-butanol has been studied in toluene and in bis(2-methoxyethyl) ether (diglyme) by IR spectroscopy at different temperatures (20–60°C). A kinetic study shows that it is first order with respect to each reactant even when the reaction is catalyzed by tin octoate. A general mathematical treatment indicates that secondary reactions may occur in some conditions of temperature, solvent and catalyst, but do not take place in our system. The activation enthalpy and entropy have been determined.
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