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Addition Reactions to Methylenecyclopropanes II:Electrophilic Additions of Diphenylmethylenecyclopropane

 

作者: E. Dunkelblum,  

 

期刊: Israel Journal of Chemistry  (WILEY Available online 1973)
卷期: Volume 11, issue 4  

页码: 557-566

 

ISSN:0021-2148

 

年代: 1973

 

DOI:10.1002/ijch.197300050

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractA number of addition reactions to diphenylmethylenecyclopropane (II) have been studied. Bromination and CF3COOH addition in CH3Cl2proceeded with ring‐opening and gave the homoallylic adducts III and VI. On the other hand bromination in glyme and water gave both unrearranged and rearranged products, III and V. Reactions with NBS in the same solvent system gave the unrearranged bromohydrin V. Oxymercuration and hydroboration proceeded without ring‐cleavage, the mercury and boron attacking mainlyβ‐ to the phenyl groups. Two cyclopropylmercury compounds VII and IX were isolated and charact

 

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