Addition Reactions to Methylenecyclopropanes II:Electrophilic Additions of Diphenylmethylenecyclopropane
作者:
E. Dunkelblum,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1973)
卷期:
Volume 11,
issue 4
页码: 557-566
ISSN:0021-2148
年代: 1973
DOI:10.1002/ijch.197300050
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractA number of addition reactions to diphenylmethylenecyclopropane (II) have been studied. Bromination and CF3COOH addition in CH3Cl2proceeded with ring‐opening and gave the homoallylic adducts III and VI. On the other hand bromination in glyme and water gave both unrearranged and rearranged products, III and V. Reactions with NBS in the same solvent system gave the unrearranged bromohydrin V. Oxymercuration and hydroboration proceeded without ring‐cleavage, the mercury and boron attacking mainlyβ‐ to the phenyl groups. Two cyclopropylmercury compounds VII and IX were isolated and charact
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