Search For A New Reagents From The Nitrosoamine Group For Spectrophotometric Determination Of Sulphur Dioxide
作者:
M. Biziuk,
E. Kozlowski,
G.E. Baiulescu,
期刊:
Analytical Letters
(Taylor Available online 1981)
卷期:
Volume 14,
issue 16
页码: 1377-1389
ISSN:0003-2719
年代: 1981
DOI:10.1080/00032718108081466
出版商: Taylor & Francis Group
关键词: Sulphur dioxide determination;spectro-photometry;p-nitrosodiphenylamine.
数据来源: Taylor
摘要:
p-Nitrosodiphenylamine as a representative of nitrosoamine group was tested as a new reagent for the spectrophotometric determination of SO2. A mixture containing: p-nitrosodiphenylamine, formaldehyde, HCl, di-methylformamide and water was added to the aqueous test solutions of sulphites forming after 5 min, a blue complex with Λmax=675 nm stable for one hour. The Lambert-Beer law was obeyed in the 0 to 50 /ug SO2/cm3range. Molar absorptivity was equal to 2000 and the specific absorption was 0.062. The investigations should lead to search for other reagents from the nitrosoamine group suitable for this purpose.
点击下载:
PDF (403KB)
返 回