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Stereospecific synthesis ofN‐(1‐phenylethyl)‐2,4,5‐triphenyloxazolidines

 

作者: Benito Alcaide,   Carmen Lopez‐Mardomingo,   Rafael Perez‐Ossorio,   Joaquin Plumet,  

 

期刊: Journal of Heterocyclic Chemistry  （WILEY Available online 1982）
卷期: Volume 19, issue 1  

页码: 45-48

 

ISSN:0022-152X

 

年代: 1982

 

DOI:10.1002/jhet.5570190106

 

出版商: Wiley‐Blackwell

 

数据来源: WILEY

 

摘要:

AbstractTreatment of the diastereoisomericN‐(1‐phenylethyl)‐1,2‐diphenyl‐2‐aminoethanols with benzaldehyde yields stereospecificallyN‐(1‐phenylethyl)‐2,4,5‐triphenyloxazolidines with four chiral centers. The configurations of these oxazolidines are established through their ring‐opening reactions with methylmagnesium iodide and subsequent oxidation

 

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