Room Temperature Phosphorescence Optosensor for Terbium
作者:
Zhilong Gong,
Zhujun Zhang,
Anyun Zhang,
期刊:
Analytical Letters
(Taylor Available online 1996)
卷期:
Volume 29,
issue 4
页码: 515-527
ISSN:0003-2719
年代: 1996
DOI:10.1080/00032719608000418
出版商: Taylor & Francis Group
关键词: Terbium;Phosphorescence;Optical Sensor
数据来源: Taylor
摘要:
A solid surface room temperature phosphorescence optosensing method has been developed for the determination of terbium(III) based on the adsorption of its binary complex with 1,4-bis (l'-phenyl-3′-methyl-5′-pyrazolone-4′-) butanedione-(1,4) (BPMPBD) onto the hydrogen form of a strong cation exchange resin packed in a flow cell in an aqueous flow system. The phosphorescence intensity is a linear function of the concentration of terbium in the range of 8x10−9M-6x10−7M, and the detection limit is 3x10−9M terbium. The response mechanism was also studied. The present optosensor has been used for the determination of trace amounts of terbium in synthetic samples with satisfactory results.
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