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Asymmetric synthesis of (2S,4S)-2,4-diaminoglutaric and (2S,3S)-2,3-diamino-2, 3-dimethylsuccinic acids using chiral Ni(II) complexes

 

作者: Yu.N.Belokon',   N.I.Chernoglazova,   A.S.Batsanov,   N.S.Garbalinskaya,   V.I.Bakhmutov,   Yu.T.Struchkov,   V.M.Belikov,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  （Springer Available online 2004）
卷期: Volume 36, issue 4  

页码: 779-784

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00962319

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.Oxidative dimerization of the Ni(II) complexes of the Schiff's base of S,R-alanine with S-2-N-(N′-benzylprolyl)aminobenzaldehyde has been carried out, to give following de-composition of the dimeric complex (2S,3S)-2,3-diamino-2,3-dimethylsuccinic acid.2.C-Alkenylation of glycine in the Ni(II) complex of its Schiff's base with S-2-N-(N′-benzylprolyl)aminobenzophenone by treatment with CH2Br2followed by decomposition of the alkenylated complex has given (2S,4S)-diaminoglutaric a

 

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