Large photoinduced refractive index changes of a polymer containing photochromic norbornadiene groups
作者:
Koichi Kinoshita,
Kazuyuki Horie,
Sin’ya Morino,
Tadatomi Nishikubo,
期刊:
Applied Physics Letters
(AIP Available online 1997)
卷期:
Volume 70,
issue 22
页码: 2940-2942
ISSN:0003-6951
年代: 1997
DOI:10.1063/1.118750
出版商: AIP
数据来源: AIP
摘要:
We prepared a polymer containing pendant norbornadiene (NBD) moieties,P(MMA0.43-co-GMA0.57-PNCA),and measured absorbance and refractive index spectra before and after photoisomerization of norbornadiene moieties. Large photoinduced refractive index changes of∼0.01were obtained at 632.8 nm, the region far from the absorption band. A quantum yield of 0.50 was obtained for the photoisomerization of NBD moieties in this polymer. These values are sufficient to make efficient channel waveguides by photoisomerization. ©1997 American Institute of Physics.
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