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Temperature Dependence of Sensitized Fluorescence in Naphthalene Crystals

 

作者: A. Hammer,   H.C. Wolf,  

 

期刊: Molecular Crystals  (Taylor Available online 1968)
卷期: Volume 4, issue 1-4  

页码: 191-193

 

ISSN:0369-1152

 

年代: 1968

 

DOI:10.1080/15421406808082911

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The mechanism of energy transport in organic molecular crystals can be studied by sensitized fluorescence. One can analyze nearly all of the experimental results on sensitized fluorescence so far reported by a hopping model.1In this model, energy is hopping from molecule to molecule with a characteristic time of about 10−13sec (incoherent exciton). Since one does not observe an activation energy for energy migration in pure organic crystals, there is no firm theoretical foundation for the hopping model, and it seems more satisfactory to explain energy transfer by a free exciton (coherent exciton) mechanism.

 

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