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Biomimetic Synthesis and Absolute Configuration of (−)-Tanzanene

 

作者: ShashikumarK. Paknikar,   KamaleshPai Fondekar,   Ralf Mayer,  

 

期刊: Natural Product Letters  （Taylor Available online 1996）
卷期: Volume 8, issue 4  

页码: 253-256

 

ISSN:1057-5634

 

年代: 1996

 

DOI:10.1080/10575639608044903

 

出版商: Taylor & Francis Group

 

关键词: (−)-tanzanene;[4+2]cycloaddition;(−)-allo-aromadendrene;6-methylene-2,4-cyclohexadiene-1-one;o-quinone methide;hetero Diels-Alder reaction;Uvaria

 

数据来源: Taylor

 

摘要:

Biomimetic synthesis of (−)-tanzanene (1) from (−)-alloaromadendrene (4) is reported. This first synthesis of (−)-tanzanene also established its absolute configuration as shown in1.

 

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