Origin of nonlinearities in the Bagley plots of thermotropic copolyesters
作者:
Paula Moldenaers,
J. Vermant,
J. Mewis,
I. Heynderickx,
期刊:
Journal of Rheology
(AIP Available online 1996)
卷期:
Volume 40,
issue 2
页码: 203-219
ISSN:0148-6055
年代: 1996
DOI:10.1122/1.550799
出版商: The Society of Rheology
关键词: Bagley plot;Orientation development in LCPs;Pressure dependence of viscosity;Liquid crystalline polymers;CAPILLARY FLOW;LIQUID CRYSTALS;ORIENTATION;POLYESTERS;POLYMERS;PRESSURE DEPENDENCE;VISCOSITY;WALL EFFECTS
数据来源: AIP
摘要:
The origin of the nonlinearity observed in Bagley plots of thermotropic copolyesters has been investigated experimentally. With the aid of a two‐piston slit rheometer the dependence of the viscosity on the hydrostatic pressure has been determined directly. This dependence only accounts for part of the nonlinearity of the Bagley plots. Using slit dies with either a convergent or a divergent entrance, concave as well as convex pressure profiles are obtained. This can only be explained by a change in the molecular orientation induced by the flow in the entrance zone. The presence of wall effects has been evaluated by measuring the pressure profiles in slits of different heights; it does not explain the nonlinearity of the Bagley plots. The origin of the nonlinearity of Bagley plots must be due to both pressure and molecular reorientation effects. The nature and importance of these reorientation effects are shown to depend on the entrance geometry.
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