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Rate of Spherulitic Crystallization with Chain Folds in Polyoxymethylene

 

作者: Eric Baer,   D. R. Carter,  

 

期刊: Journal of Applied Physics  (AIP Available online 1964)
卷期: Volume 35, issue 6  

页码: 1895-1897

 

ISSN:0021-8979

 

年代: 1964

 

DOI:10.1063/1.1713765

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Spherulitic growth rate data for polyoxymethylene have been successfully analyzed with the recently proposed nucleation theory by Hoffman and co‐workers that assumes a coherent nucleation mechanism. Lamellar step heights, which were calculated as a function of the crystallization temperature, were in good agreement with experimental values obtained by Geil who used small angle x‐ray scattering. The surface free energy of the nucleus and the end free energy of the fold surface were calculated to be 10.5 and 26 ergs/cm2, respectively. These reasonable values lend further support to this kinetic analysis.

 

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