Azimuthally travelling ocean waves are seldom well imaged by microwave real aperture radar (RAR) operating with conventional HH or VV polarizations. Attenuation of image intensity modulation in the azimuthal direction implies that ocean wave spectra derived from such images also will not be accurate. Real aperture radar cross-section modulation by long ocean waves is normally attributed to two principal sources, tilt modulation and hydrodynamic modulation. In ocean radar images both of these modulation sources are significantly attenuated in the azimuthal direction. Therefore, complete two-dimensionalk-space wave spectra derived from microwave data often are quite different than physical ocean spectra. This paper uses fully-polarimetric radar measurements of ocean backscatter to identify a new source of backscatter modulation that is strongest in the azimuthal direction. This modulation source has potential for augmenting tilt and hydrodynamic modulation sources in the azimuthal direction where their weakness causes poor wave visibility. The predicted improvement in the measurement of ocean wave spectra using an optimized polarization is investigated by means of aRARocean imaging model. Fully-polarimetric, and conventional, radar spectrometers are proposed which are specifically optimized to sense wave-tilts in the azimuthal direction.