Cooperative interaction of carboxymethyl cellulose with C.I. basic red 18 in aqueous solution
作者:
Soomin Pak,
Yasuko Ando,
Juichi Koshikawa,
Toshiro Iijima,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1984)
卷期:
Volume 23,
issue 1
页码: 85-91
ISSN:0022-2348
年代: 1984
DOI:10.1080/00222348408229363
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The binding isotherms of C.I. Basic Red 18 with carboxy-methyl cellulose having various degrees of substitution have been determined in an acetate buffer at pH 4.2 and 30°C by a dynamic dialysis technique. The isotherms show a sigmoidal increase of binding with increasing free dye concentration in solution. The results strongly suggest a cooperative mode of binding. In the interpretation of the results, McGhee and von Hippel's theory considering cooperativity in binding was used. The intrinsic binding constant K, the number of consecutive polymer residues occupied by a single dye molecule n, and the cooperativity parameter were determined. A molecular mechanism of binding is proposed.
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