Phase-Sensitive A. C. Polapography of 1, 10-Phemanthroline Determination of Trace Concentrations of Iron
作者:
G.A. East,
S. Rath,
期刊:
Analytical Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 12
页码: 2277-2292
ISSN:0003-2719
年代: 1988
DOI:10.1080/00032718808059909
出版商: Taylor & Francis Group
关键词: Phase-sensitive a. c. polaroqraphy;iron determination;1, 10-phenanthroline;trace analysis
数据来源: Taylor
摘要:
Indirect determination of trace concentrations of iron was studied by monitoring the decrease of the a. c. polarographic wave of 1, 10- phenan tli rol i ne (phen). Fundamental harmonic, with current measured at Φ = 90°, was utilized. The best supporting electrolyte was found to be a 0.6 H NaClO4solution of pH 4.5 with acetate buffer. The approach consists in running polarograns for the supporting electrolyte containing buffer and phen, subsequent to sample addition, and after each addition of standard, respectively. The effect of pH, buffer system, some common anions and iron(III) was investigated. The method has been applied to the determination of iron in pure samples, reference standard material, and tap water. The detection limit was 4 ng mL−1.
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