Nature of the Unpaired Electron Orbital in Some Low Spin Oxygen-Co Complexes
作者:
Hideo Kon,
NormanE. Sharpless,
期刊:
Spectroscopy Letters
(Taylor Available online 1968)
卷期:
Volume 1,
issue 1
页码: 49-54
ISSN:0038-7010
年代: 1968
DOI:10.1080/00387016808049943
出版商: Taylor & Francis Group
关键词: spin distribution;superoxide ion;cobalt complexes
数据来源: Taylor
摘要:
The CoIIcomplexes, Co(II)-bissalicylal-3,3′-diimino-di-n-propylamine peroxide I and decaammine-μ-peroxodicobalt cation II, were investigated by the electron spin resonance (esr). On the basis of the observed esr parameters, it was concluded that the unpaired electron is largely localized on the O2group and, therefore, these complexes are better described as super-oxides. The equilibrium in solution of I between the paramagnetic and dia-magnetic forms implied by the previous studies was also demonstrated.
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