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Anodic Potential‐Homo Energy Relations of Fluorene Derivatives

 

作者: Ş. Şen,   N. Çelebi,   L. Türker,   A. M. Önal,  

 

期刊: Bulletin des Sociétés Chimiques Belges  （WILEY Available online 1993）
卷期: Volume 102, issue 9  

页码: 583-587

 

ISSN:0037-9646

 

年代: 1993

 

DOI:10.1002/bscb.19931020904

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

数据来源: WILEY

 

摘要:

AbstractAnodic oxidation peak potentials (Ep,a) of some fluorene derivatives were measured on a Pt° electrode versus Ag°/Ag+in acetonitrile‐TBAFB by cyclic voltammetry. The highest occupied molecular orbital (HOMO) energies of the compounds were calculated within the Huckel molecular orbital (HMO) framework. The measured Ep,avalues were correlated to theoretical HOMO energies with a linear regression mo

 

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