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Kinetics of the thermal decomposition of bis‐pentafluorine sulfur peroxide in the presence of carbon monoxide

 

作者: J. Czarnowski,   H. J. Schumacher,  

 

期刊: International Journal of Chemical Kinetics  (WILEY Available online 1978)
卷期: Volume 10, issue 1  

页码: 111-116

 

ISSN:0538-8066

 

年代: 1978

 

DOI:10.1002/kin.550100109

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe thermal decomposition of F5SOOSF5, P, in the presence of CO has been investigated between 130.1° and 161.9°C at total pressures between 50 and 600 torr. The reaction is homogeneous, and the only final products formed are CO2and S2F10. The rate of reaction is proportional to the pressure of P. The partial pressures of CO and O2and the total pressure have no influence on the course of reaction:\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{d\left[P \right]}}{{dt}} = k\left[P \right] $$\end{document}The results are explained by the following mechanis

 

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