Lignin-Derived Quinones as Pulping Additives
作者:
JohnC. Wozniak,
DonaldR. Dimmel,
EarlW. Malcolm,
期刊:
Journal of Wood Chemistry and Technology
(Taylor Available online 1989)
卷期:
Volume 9,
issue 4
页码: 535-548
ISSN:0277-3813
年代: 1989
DOI:10.1080/02773818908050314
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Quinones, which may be generated from lignin and lignin-related materials, and their Diels-Alder derivatives were evaluated as delignification promoters. Compared to anthraquinone at a 0.1% addition level, benzoquinones and oxidized lignin showed little or no effect. However, some naphthoquinones were found effective at higher addition levels, and a mixture of dimethyl-anthraquinone isomers was found to be superior to anthraquinone. The substituted anthraquinones, phenanthrenequinones, and fully aromatized naphthoquinones appear to function in a reduction/oxidation cycle such as that proposed for anthraquinone.
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