首页   按字顺浏览 期刊浏览 卷期浏览 The Kinetic Deuterium Isotope Effect of Proton Transfer Reactions in Solution
The Kinetic Deuterium Isotope Effect of Proton Transfer Reactions in Solution

 

作者: J. Sühnel,  

 

期刊: Isotopenpraxis Isotopes in Environmental and Health Studies  （Taylor Available online 1986）
卷期: Volume 22, issue 3  

页码: 73-80

 

ISSN:0021-1915

 

年代: 1986

 

DOI:10.1080/10256018608623605

 

出版商: Taylor & Francis Group

 

关键词: activation energy;deuterium;intermolecular forces;isotope effects;pressure dependence;reaction kinetics;statistical mechanics;tunnel effect

 

数据来源: Taylor

 

摘要:

The theoretical models for the treatment of the kinetic isotope effect of proton-transfer reactions (tunneling, Marcus and quantum-statistical mechanical model) are described. Scope and limits of these models are discussed with respect to intermolecular interaction, free energy relations, temperature, solvent and pressure dependence, and ultrafast protontransfer.

 

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