Studies on formaldehyde resins, 19. General base catalysis in hydroxymethylation of melamine with formaldehyde
作者:
Kenji Sato,
Takeo Konakahara,
Mikio Kawashima,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 4
页码: 875-881
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830411
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractHydroxymethylation of melamine with formaldehyde to formN‐(hydroxymethyl)melamine (2,4‐diamino‐6‐hydroxymethylamino‐1,3,5‐triazine) was investigated kinetically by the use of hydrogen phosphate/phosphate buffers in aqueous media at pH 11 − 12. This reaction was found to follow a general base catalysis which results from the kinetic investigation, showing that the reaction takes place by a concerted mechanism involving base, melamine, and formaldehyde. This mechanism differs from that of the base catalyzed hydroxymethylation of phenol or benzamide with formaldehyde, because the acidic phenol and benzamide easily form their conjugate bases by addition of the basic catalyst in a preceding equ
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