Solubility of Anthracene in Binary Carbon Tetrachloride + Alkane Solvent Mixtures
作者:
SherylA. Tucker,
WilliamE. Acree,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1989)
卷期:
Volume 19,
issue 2
页码: 73-79
ISSN:0031-9104
年代: 1989
DOI:10.1080/00319108908028437
出版商: Taylor & Francis Group
关键词: Anthracene solubilities;solubilities in binary solvents;solid-liquid equilibria
数据来源: Taylor
摘要:
Experimental solubilities are reported for anthracene in binary solvent mixtures containing carbon tetrachloride withn-hexane,n-heptane,n-octane, cyclohexane, methylcyclohexane and isooctane at 25°C. Results of these measurements, combined with the excess Gibbs free energies of the binary solvents, are used to test predictive expressions derived from the nearly ideal binary solvent (NIBS) model. Expressions based on a volume fraction average of solute properties in the two pure solvents predict anthracene solubilities to within a maximum deviation of 4.5% and an overall average deviation of 1.8%.
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