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A garnet population in Yellowknife schist, Canada

 

作者: R. KRETZ,  

 

期刊: Journal of Metamorphic Geology  (WILEY Available online 1993)
卷期: Volume 11, issue 1  

页码: 101-120

 

ISSN:0263-4929

 

年代: 1993

 

DOI:10.1111/j.1525-1314.1993.tb00134.x

 

出版商: Blackwell Publishing Ltd

 

关键词: compositional zoning;crystal shape;fractional crystallization;garnet;growth rate;nucleation rate;reaction rate;size distribution;spatial distribution;Yellowknife thermal dome

 

数据来源: WILEY

 

摘要:

AbstractData are presented on a garnet population in a specimen of garnet‐biotite‐plagioclase‐quartz schist from the cordierite zone of an Archaean thermal dome in the Southern Slave Province of the Canadian Shield. Garnet crystals are bounded by planar dodecahedral faces and by trapezohedral faces which on the 10‐μm scale are corrugated. Crystal distribution, as revealed by dissection of a small cubic volume of rock, is random. The size distribution is normal, with a mean diameter of 0.81 mm and a standard deviation of 0.32 mm. In the largest crystal of the population (mean radius 0.83 mm), [Mn] = 100 Mn/(Fe + Mg + Mn + Ca) decreases from 14.5 at the centre to 7.5 and then increases in the outer margin to 8.5; [Fe]increases continuously from 67 at the centre to 77 at the surface; [Mg] increases from 12.5 to 13.5 and then falls sharply to 11; [Ca]remains unchanged at 4.0 and then drops to 3.3. Progressively smaller crystals have progressively lower [Mn] and higher [Fe]concentrations at their centres, while all crystals have the same margin composition. Growth vectors extending from given concentration contours to crystal surfaces are of equal length regardless of the size of the crystal in which the vector is located.A garnet‐forming model is presented in which reaction was initiated by a rise in temperature. Nucleation sites were randomly selected. The nucleation rate increased with time and then declined. Crystal faces advanced at a constant linear rate, which implies an increase in volume proportional to surface area. Initially, the composition of garnet deposited on crystal surfaces was determined by van Laar equations of equilibrium, which demanded the withdrawal of Mn and Fe from within chlorite crystals. This transfer reaction was then accompanied by an ion exchange reaction which moved Mn and Fe to garnet surfaces from biotite, in exchange for Mg. The exchange reaction provides an explanation for the high overall concentration of Mn and Fe in garnet and for the observed Mn and Mg reversals in the margins of crystals. The increase of garnet volume in the garnet population is found to be parabolic

 

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