1,3‐Dipolar cycloaddition of diazocompounds to 1‐alkenylboronic esters
作者:
Mohammed Jazouli,
Bertrand Carboni,
Robert Carrié,
Mohammed Soufiaoui,
Loïc Toupet,
期刊:
Heteroatom Chemistry
(WILEY Available online 1994)
卷期:
Volume 5,
issue 5‐6
页码: 513-518
ISSN:1042-7163
年代: 1994
DOI:10.1002/hc.520050516
出版商: VCH Publishers, Inc.
数据来源: WILEY
摘要:
AbstractA variety of diazo compounds was added to the parent vinylboronic ester derived from pinacol. The reactivity of some substituted 1‐alkenylboronic esters is also briefly examined. The nonisolated primary adducts spontaneously rearrange via a 1,3‐boron migration and lead to 1‐borylated‐2‐pyrazolines. The structure of one of these compounds has been established by X‐ray diffracti
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