AbstractSix stations along the Upper Rhone River above Lake Geneva were sampled by continuous flow centrifuge for recovery of suspended sediment. The samples were taken four times, once in 1982 and three times in 1983. In addition the mouth of the river was sampled in a like manner every two weeks during 1982 until August 1983. Samples were analysed for the major elements SiO2, Al2O3, K2O, MgO, Na2O, CaO, and Fe2O3; for trace elements, Zn, Cu, Ni, Mn, and Cr; for Org. C and Kjeldahl N; and the forms of phosphorus bound as Organic P (OP), Apatite P (AP), and Non Apatite Inorganic P (NAIP). The major elements and trace metals confirmed that there is virtually no change in the major geochemical characteristics of the suspended solids in the Rhone, spatially or temporally, indicating that this river is a well‐mixed sedimentary system. AP also remained consistent in concentration throughout the year. Sediment recovered during the winter low flow, low turbidity period has been designated SED 1 whereas sediment from the high flow, high turbidity summer condition of the river has been designated SED 2. Org C, OP, and NAIP show a dramatic decrease in concentration from SED 1 to SED 2. The decline is ascribed to dilution of a relatively constant supply of organic matter and phosphorus derived mainly from point source sewage treatment plants to the Rhone. This results in variable partitioning of the OP/NAIP and Org C under the different turbidity condition in the river between winter and summer. This interpretation is confirmed by a low and consistent C‐N ratio which except for March remains below 10. Higher values in March may be indicative of soil erosion during spring melt in the agricultural lands of the Rhone Valley. The estimated proportion of particulate bio‐available phosphorus is 14 per cent for SED 1 and 7 per cent for SED 2. These low values would suggest that there would be no observable direct effect on the primary production of the receiving waters of Lake Geneva, which would thus respond only to the cumulative loading of phosphorus from the Rhone