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Inter‐Particle Interference Effects in the Small Angle X‐Ray Scattering from Fine Powders

 

作者: Louis H. Lund,   George H. Vineyard,  

 

期刊: Journal of Applied Physics  (AIP Available online 1949)
卷期: Volume 20, issue 6  

页码: 593-597

 

ISSN:0021-8979

 

年代: 1949

 

DOI:10.1063/1.1698433

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Simple formulas for calculating the small angle x‐ray scattering from aggregates of identical spherical particles, taking into account the interference between different particles, are given. The case of independent clumps of particles and the case of a more general arrangement describable by a radial density function are considered. Calculated curves of scattered intensityvs.angle for likely arrangements of both types are presented. The assumption that each particle scatters independently is seen to be a poor approximation whenever there is a significant amount of clumping or whenever the average density of the sample is as much as one third of the density corresponding to close packing. Estimates of particle size from the small angle scattering are shown to be seriously affected.

 

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