First Examples of Long Range Magnetic Ordering of Structurally Characterized Pentachloroferrate III Di-Anions: FeCl52-, and Its Methanol and Aquo Adducts
作者:
W.M. Reiff,
B.D. James,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 274,
issue 1
页码: 41-49
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508031864
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A. C. susceptibility and iron-57 Mossbauer spectroscopy measurements are used to investigate the first examples of cooperative magnetic ordering phenomena for FeCl32-anions and the related methanol and aquo adducts. Depending on the counter cation and/or solvate identity examples of uncanted antiferromagnetic and canted (weakly ferromagnetic) three dimensional order are observed with critical temperatures - 7K.
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