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Intercluster Links—A Mechanism for Flow‐Induced Crystallization of Polymer Melts

 

作者: R. B. Williamson,   W. F. Busse,  

 

期刊: Journal of Applied Physics  (AIP Available online 1967)
卷期: Volume 38, issue 11  

页码: 4187-4196

 

ISSN:0021-8979

 

年代: 1967

 

DOI:10.1063/1.1709103

 

出版商: AIP

 

数据来源: AIP

 

摘要:

An experimental study and review of the literature on the oriented crystallization of high polymers was made to develop an understanding of how ``row‐nucleated'' or shishkebab microstructures and the fibrillar links between lamellar crystals may be formed. A new mechanism is proposed for the formation of the fiber nuclei in flowing melts, based on the mechanical alignment and extension of molecules that are entangled with, and extend between, two or more rotating clusters in the melt. Similar alignment of molecules can occur when entangled clusters are pulled to different lamellar crystals during crystallization, producing intercrystallic links.

 

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