Intercluster Links—A Mechanism for Flow‐Induced Crystallization of Polymer Melts
作者:
R. B. Williamson,
W. F. Busse,
期刊:
Journal of Applied Physics
(AIP Available online 1967)
卷期:
Volume 38,
issue 11
页码: 4187-4196
ISSN:0021-8979
年代: 1967
DOI:10.1063/1.1709103
出版商: AIP
数据来源: AIP
摘要:
An experimental study and review of the literature on the oriented crystallization of high polymers was made to develop an understanding of how ``row‐nucleated'' or shishkebab microstructures and the fibrillar links between lamellar crystals may be formed. A new mechanism is proposed for the formation of the fiber nuclei in flowing melts, based on the mechanical alignment and extension of molecules that are entangled with, and extend between, two or more rotating clusters in the melt. Similar alignment of molecules can occur when entangled clusters are pulled to different lamellar crystals during crystallization, producing intercrystallic links.
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