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Spectroscopic Investigation on Charge Transfer Complexes Formed in the Reaction of Π-Electron Acceptors with the Donor Cyclic base 1,4,10,13-Tetraoxa-7,16-Diazacyclooctadecane

 

作者: E.M. Nour,   A.S. Barakat,   A. Amer,   A. Ebrahim,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1999)
卷期: Volume 32, issue 1  

页码: 115-124

 

ISSN:0038-7010

 

年代: 1999

 

DOI:10.1080/00387019909349971

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The interaction of the cyclic base 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (TODACOD) with different π-electron acceptors have been studied spectrophotometrically in CHCl3. These π-electron acceptors are 1-chloro-2,4,6-trinitrobenzene (picryl chloride), 7,7', 8,8'-tetracyanoquinone (TCNQ) and tetrachloro-p-benzoquinone (chloranil). The results indicate the formation of 1:4 charge transfer complexes with the general structures [(TODACOD)(Accept)4]. The charge transfer absorptions as well as the infrared spectra of these complexes are obtained.

 

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