Spectroscopic Investigation on Charge Transfer Complexes Formed in the Reaction of Π-Electron Acceptors with the Donor Cyclic base 1,4,10,13-Tetraoxa-7,16-Diazacyclooctadecane
作者:
E.M. Nour,
A.S. Barakat,
A. Amer,
A. Ebrahim,
期刊:
Spectroscopy Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 1
页码: 115-124
ISSN:0038-7010
年代: 1999
DOI:10.1080/00387019909349971
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The interaction of the cyclic base 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (TODACOD) with different π-electron acceptors have been studied spectrophotometrically in CHCl3. These π-electron acceptors are 1-chloro-2,4,6-trinitrobenzene (picryl chloride), 7,7', 8,8'-tetracyanoquinone (TCNQ) and tetrachloro-p-benzoquinone (chloranil). The results indicate the formation of 1:4 charge transfer complexes with the general structures [(TODACOD)(Accept)4]. The charge transfer absorptions as well as the infrared spectra of these complexes are obtained.
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