首页   按字顺浏览 期刊浏览 卷期浏览 Apparatus for measuring pressure–volume–temperature relationships of polyme...
Apparatus for measuring pressure–volume–temperature relationships of polymers to 350 °C and 2200 kg/cm2

 

作者: P. Zoller,   P. Bolli,   V. Pahud,   H. Ackermann,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1976)
卷期: Volume 47, issue 8  

页码: 948-952

 

ISSN:0034-6748

 

年代: 1976

 

DOI:10.1063/1.1134779

 

出版商: AIP

 

数据来源: AIP

 

摘要:

An apparatus for determining the specific volume of solid and liquid polymers as a function of pressure (to 2200 kg/cm2) and temperature (30–350 °C) has been constructed. It is based on Bridgman’s bellows method and makes use of a linear variable differential transformer (LVDT) mounted outside the pressure vessel to measure the length changes of the bellows. The off‐null output of the LVDT drives a digital indicator, displaying length changes with an accuracy of 0.01 mm, corresponding to a volume change of 10−3cm3. Typical samples weigh about 2 g. Volume changes of the sample are calculated from the bellows displacement using the pvT properties of the confining mercury, and by using a calibration function determined in a separate experiment. This apparatus is capable of measuring specific volume changes of polymers with an accuracy of 0.001–0.002 cm3/g. Results for a commercial polystyrene in the glassy and liquid states are given.

 

点击下载:  PDF (393KB)



返 回