首页   按字顺浏览 期刊浏览 卷期浏览 Studies on Thermodynamic Properties of Polyvalent Electrolytes from E. M. F. Measuremen...
Studies on Thermodynamic Properties of Polyvalent Electrolytes from E. M. F. Measurements. I. The Silver‐Silver Chromate Electrode

 

作者: Kuan Pan,  

 

期刊: Journal of the Chinese Chemical Society  (WILEY Available online 1954)
卷期: Volume 1, issue 1  

页码: 1-15

 

ISSN:0009-4536

 

年代: 1954

 

DOI:10.1002/jccs.195400001

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

Abstract(1)The solubility product of silver chromate was determined from e.m.f. of the cell,by extrapolation of the function,to x=0 and then m=0. K s.p. in the temperature range of 20° to 40°C is expressed by(2)The molal heat of solution of silver chromate was evaluated from the temperature coefficient of 1n Ks.p. and given by(3)The standard potential of the Ag; Ag3CrO4(s), CrO4−electrode was evaluated from E° = π°Ag;Ag+− k log Ks.p. It is given by(4)The molal free energy change for solution of Ag2CrO4(s) is given by(5)The molal heat, free energy and entropy change of formation of silver chromate from its elements at 25°C were

 

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