首页   按字顺浏览 期刊浏览 卷期浏览 Neutron and Raman Scattering Studies of the Lattice and Methyl-Group Dynamics in Solidp...
Neutron and Raman Scattering Studies of the Lattice and Methyl-Group Dynamics in Solidp-Xylene

 

作者: J. Kalus,   M. Monkenbusch,   I. Natkaniec,   M. Prager,   J. Wolfrum,   F. Wörlen,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 268, issue 1  

页码: 1-20

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508030989

 

出版商: Taylor & Francis Group

 

关键词: Lattice dynamics;molecular crystals

 

数据来源: Taylor

 

摘要:

Solidp-C6H4(CH3)2andp-C6H4(CD3)2have been studied over a temperature range from 10 K up to the melting point of ∼ 287 K by Raman- and Incoherent Inelastic Neutron-Scattering(IINS). The methyl torsion frequencies deduced from the Raman- and IINS-spectra are different because of the strong coupling of these modes with phonons and their dispersion in the Brillouin zone. A decrease in frequencies and a strong broadening, especially of the high frequency phonons where methyl torsions are predominant, have been observed in Raman- and IINS-spectra with increasing temperature. A lattice dynamics model based on the atom-atom potential set IVa of parameters given by Williams can, after some small modifications, satisfactorily explain the dynamics of ap-xylene crystal. Modified potential parameters better reproduce the experimental data and allow one to study the coupling of the internal methyl rotation with the lattice modes in more detail.

 

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