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Crystallization behavior of high-density polyethylene in an oriented blend with polypropylene

 

作者: Y. Nishio,   T. Yamane,   T. Takahashi,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1984)
卷期: Volume 23, issue 1  

页码: 17-27

 

ISSN:0022-2348

 

年代: 1984

 

DOI:10.1080/00222348408229360

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Crystallization behavior of high-density polyethylene blended with polypropylene was investigated in the oriented system, using wide-angle and small-angle x-ray diffractometries and electron microscopy. When polypropylene/polyethylene (PP/PE) drawn blends were heat treated in the temperature range above the melting point of PE, a new orientation texture of PE was produced during melt-recrystallization in the PP matrix. The majority of PE crystallites are aligned with their (110) planes perpendicular to the draw direction of the film specimen. Furthermore, well-developed lamellar structure is formed in the PE phase, along the crystallite b axes oriented preferentially at angles of 30-40° to the draw direction. The reason that such a distinctive orientation texture of PE develops in the blend with PP is discussed in some detail. As a possible explanation, it is suggested that thermal shrinking stress greatly affects the crystallization behavior of PE.

 

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