Thermochemical Investigation of Molecular Complexation: Estimation of Anthracene-ethyl Acetate and Anthracene-diethyl Adipate Association Parameters from Measured Solubility Data
作者:
AnitaI. Zvaigzne,
WilliamE. Acree,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1991)
卷期:
Volume 24,
issue 1-2
页码: 31-42
ISSN:0031-9104
年代: 1991
DOI:10.1080/00319109108030646
出版商: Taylor & Francis Group
关键词: Anthracene solubilities;molecular complexation;binary solvents;calculation of association constants
数据来源: Taylor
摘要:
Experimental solubilities are reported for anthracene in binary mixtures containing ethyl acetate or diethyl adipate withn-hexane,n-heptane,n-octane, cyclohexane, methylcyclohexane and isooctane at 25°C. Results of these measurements, combined with estimates for the excess Gibbs free energies of the binary solvents, are used to evaluate equilibrium constants for presumed anthracene-ethyl acetate and anthracene-diethyl adipate molecular complexes using the Extended Nearly Ideal Binary Solvent model. A single association constant was needed for each assumed complex in order to describe the experimental data to within an average deviation of 2%, though the numerical value did vary with inert hydrocarbon cosolvent. Poor estimates for the binary Gibbs free energies contributed significantly to the equilibrium constant variation.
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